Mono-copper far more active than analogous di-copper …
Although dicopper(II) complex 2 is easier to reduce than the analogous monocopper(II) complex 1 in MeCN (E 1/2 (ΔE): 2 −1.20(0.12) V, 1 −1.39(0.09) V, vs. 0.01 M AgNO 3 /Ag), electrocatalytic HER testing of dicopper complex 2·4H 2 O, in MeCN with 80 equivalents of acetic acid, revealed it was inactive, in stark contrast to the high and ...
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